The love of Pepper's life. Tony is everything from the most important person in the world to her to the biggest pain in her ass. No matter what term she's using for him at the moment, Tony is never not the most important person to her and the owner of her heart.
Steve Rogers
For the most part Steve has always been just words on paper and complaints by Tony for Pepper. Upon meeting him he seemed nice enough, but nothing to write home about. After meeting his doppleganger in the maze she's started to think there's more to Steve then what he portrays on the outside and would like to get to know him better. One day, if he opens up and shows that he's more then just the suit and iconic name, he might even become a good friend. In the end she really just wants to know the Steve that she saw inside the maze more.
James Barnes
A sweet guy with a lot of problems. Pepper wants to help him out as much as she can, especially after his public mental spazz. She has no idea that they're from the same world or that 'James' is the same 'Bucky' that is Steve's best friend.
Trip
They've spoken a few times and she thinks he's a pretty good kid. She appreciated his sarcasm and sass very much, but he's also very young so she wants to keep an eye on him.
Minako Arisato
A good kid, Minako has already warmed her way into Pepper's heart. Pepper wants to keep the girl busy to help keep her mind off the fact that her friends recently left the world they're stuck on. Potentially thinking of asking Minako to help her start up a business.
Oz Vessalius
Pepper can't help but be charmed by Oz whenever they talk. He reminds her very much of Tony and to that end she can't help having a special place in her heart for the boy she barely knows. She wants to get to know him better.
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